D. Adam & Associates -- Making the difference -- with Armaglaze long life coating.

ARMAGLAZE LONG LIFE 2-PACK COATING HARDNER - PACK B  -  SDS - SAFETY DATA SHEET.

SECTION 1: Identification of the substance/mixture and of the company/undertaking.                                            

1.1 Product identifier For professional use only:

Trade name:

Armaglaze 2-pack long life coating

1.2 Relevant identified uses of the substance or mixture and uses advised against Surface Coating · Application of the substance / the mixture:

Surface Coating Hardner - Pack B.

1.3 Details of the supplier of the safety data sheet .

Supplier: D Adam & Associates, 1 west End Units, "Charlesfield", ST Boswells, Melrose, TD6 0HH Scotland, UK.

Tel: +44 (0) 1835 268120,  Mob:07880 805478.

E-mail: dougadam70@gmail.com   Web site: www.enviroguard-anti-graffiti.co.uk

1.4 Emergency telephone number:

44 (0) 1835 268120  (Business hours)

 

SECTION 2: Hazards identification.                                                                                                                                               

2.1 Classification of the substance or mixture ·

Classification according to Regulation (EC) No 1272/2008

None

Flam. Liq.     3 H226 Flammable liquid and vapour.

Acute Tox.   4 H332 Harmful if inhaled.

Skin Irrit.     2 H315 Causes skin irritation.

Eye Irrit.      2 H319 Causes serious eye irritation.

Skin Sens.   1 H317 May cause an allergic skin reaction.

STOT SE      3 H335 May cause respiratory irritation.

STOT RE      2 H373 May cause damage to organs through prolonged or repeated exposure.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008

The product is classified and labelled according to the CLP regulation.

Hazard pictograms:

 

 

 

 

 

 

 

         GHS02                             GHS07                                  GHS08 

Signal word Warning

Hazard-determining components of labelling:

Hexamethylene-1,6-diisocyanate Homopolymer

Xylene (mix) hexamethylene-1,6 diisocyanate

Hazard statements

H226 :  Flammable liquid and vapour.

H332 :  Harmful if inhaled.

H315 :  Causes skin irritation.

H319 :  Causes serious eye irritation.

H317 :  May cause an allergic skin reaction.

H335 :  May cause respiratory irritation.

H373 :  May cause damage to organs through prolonged or repeated exposure.

Precautionary statements:

P210 :  Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P241 :  Use explosion-proof electrical/ventilating/lighting equipment.

P303+P361+P353 IF ON SKIN (or hair):  Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES:  Rinse cautiously with water for several minutes.

                                                     Remove contact lenses, if present and easy to do. Continue rinsing.

P405 :  Store locked up.

P501 :  Dispose of contents/container in accordance with local/regional/national/international regulations.

Additional information:

Contains isocyanates. May produce an allergic reaction.

 

2.3 Other hazards · Results of PBT and vPvB assessment

PBT: Not applicable.

vPvB: Not applicable.

 

SECTION 3: Composition/information on ingredients.                                                                                                            

3.2 Chemical characterisation: Mixtures

Description: Mixture of substances listed below with nonhazardous additions.

Dangerous components:

Hexamethylene-1,6-diisocyanate Homopolymer  (50-100%)

CAS: 28182-81-2    NLP: 500-060-2                                                                    Acute Tox. 4, H332; Skin Sens. 1, H317;

                                                                                                                                STOT SE 3, H335 50-100%

Xylene (mix) (10-25%)

CAS: 1330-20-7    EINECS: 215-535-7    Reg.nr.: 01-2119488216-32-xxxx     Flam. Liq. 3, H226; STOT RE 2, H373; Asp. Tox 1                                                                                                                                    H304; Acute Tox. 4, H312; Acute Tox. 4, H332;                                                                                                                                      Skin Irrit. 2, H315; Eye Irrit. 2, H319;

                                                                                                                                  STOT SE 3, H335

2-methoxy-1-methylehyl acetate  (10-20%)

CAS: 108-65-6    EINECS: 203-603-9    Reg.nr.: 01-2119475791-29                  Flam. Liq. 3, H226  

hexamethylene-1,6 diisocyanate  (<2.5%)

CAS: 822-06-0    EINECS: 212-485-8    Reg.nr.: 01-2119457571-37-0000/5/6  Acute Tox. 2, H330; d~ Resp. Sens. 1, H334;                                                                                                                                         Acute Tox. 4, H302; Skin Irrit. 2, H315;

                                                                                                                                     Eye Irrit. 2, H319; Skin Sens. 1, H317;

                                                                                                                                     STOT SE 3, H335 ≤2.5%

Additional information:

Hexamethylene-1,6-diisocyanate wt% 0.40mm.

For wording of the listed phrases and hazardsrefer to section 16.

SECTION 4: First aid measures.                                                                                                                                                       

4.1 Description of first aid measures

General information:

Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

After inhalation:

In case of unconsciousness place the patient stably in side position for transportation.

If the aerosol or vapour in inhaled in high concentrations, take the person into fresh air, keep warm and let rest.

If there is difficulty in breathing, medical advice is required. Supply fresh air and call for a doctor.

In case of unconsciousness place patient stably in side position for transportation.

Supply fresh air; consult doctor in case of complaints.

After skin contact:

Immediately wash with water and soap and rinse thoroughly. Remove contaminated clothing.

Immediately rinse with water.

After eye contact:

Hold the eye open and rinse with (preferably) luke warm water for a sufficiently long period of time (at least 10 minutes). Contact a doctor or opthalmologist. Rinse opened eye for several minutes under running water.

If symptoms persist, consult a doctor.

After swallowing:

DO NOT induce the patient to vomit, medical advice is required.

Do not induce vomiting; call for medical help immediately and show safety datasheet or label.

4.2 Most important symptoms and effects, both acute and delayed

No further relevant information available.

4.3 Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

 

SECTION 5: Firefighting measures .                                                                                                                                            

5.1 Extinguishing media:

Suitable extinguishing agents:

CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

For safety reasons unsuitable extinguishing agents:

Water with full jet,

5.2 Special hazards arising from the substance or mixture:

During heating or in case of fire poisonous gases are produced.

5.3 Advice for firefighters  

Protective equipment:

Mount respiratory protective device. In the event of fire, carbon monoxide, nitrogen oxides, isoyanate vapour and traces of hydrogen cyanide may be released. Firemen must wear self-contained breathing apparatus.

Do not allow contaminated extinguishing water to enter the soil, groundwater or surface waters.

 

SECTION 6: Accidental release measures.                                                                                                                                   

 6.1 Personal precautions, protective equipment and emergency procedures:

Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away.

6.2 Environmental precautions:

Prevent seepage into sewage system, work pits and cellars. Do not allow to enter sewers/ surface or ground water.

6.3 Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation.

6.4 Reference to other sections:

See Section 7 for information on safe handling.

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information. GB.

SECTION 7: Handling and storage.                                                                                                                                               

 7.1 Precautions for safe handling:

Keep receptacles tightly sealed. Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. · Information about fire - and explosion protection:

Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Keep respiratory protective device available.

7.2 Conditions for safe storage, including any incompatibilities

Storage:

Requirements to be met by storerooms and receptacles:

tore separately from oxidising agents, strongly alkaline and strongly acidic materials, amines, alcohols and water · Information about storage in one common storage facility:

Store separately from oxidising agents, strongly alkaline, strongly acidic materials, amines, alcohols and water.

Further information about storage conditions:

Keep receptacle tightly sealed and in a well-ventilated place. Keep away from heat.

7.3 Specific end use(s):

No further relevant information available.

 

SECTION 8: Exposure controls/personal protection.                                                                                                                

Additional information about design of technical facilities:

No further data; see item 7. ·

8.1 Control parameters 

Ingredients with limit values that require monitoring at the workplace:

28182-81-2 Hexamethylene-1,6-diisocyanate Homopolymer

EH40 WEL Short-term value: 0.07 mg/m³

EH40 WEL Long-term value: 0.02 mg/m³

1330-20-7 Xylene (mix)

WEL Short-term value: 441 mg/m³, 100 ppm

WEL  Long-term value: 220 mg/m³, 50 ppm

Sk; BMGV

108-65-6 2-methoxy-1-methylethyl acetate

WEL Short-term value: 548 mg/m³, 100 ppm

WEL  Long-term value: 274 mg/m³, 50 ppm

Sk

822-06-0 hexamethylene-1,6 diisocyanate

WEL Short-term value: 0.07 mg/m³

WEL Long-term value: 0.02 mg/m³

Sen; as -NCO

 DNELs

28182-81-2 Hexamethylene-1,6-diisocyanate Homopolymer

Inhalative DNEL 0.5 mg/m³ (Ind)

1330-20-7 Xylene (mix)

Dermal DNEL 108 mg/day (Con) 180 mg/day (Ind)

Inhalative DNEL 14.8 mg/m³ (Con) 77 mg/m³ (Ind)

108-65-6 2-methoxy-1-methylethyl acetate

Oral DNEL 1.67 mg/day (Con)

Dermal DNEL 54.8 mg/day (Con) 153.5 mg/day (Ind)

Inhalative DNEL 33 mg/m³ (Con) 275 mg/m³ (Ind)

822-06-0 hexamethylene-1,6 diisocyanate Inhalative

DNEL 0.035 mg/m³ (Ind)

PNECs

CAS No. 1330-20-7 Xylene mixed isomers

Fresh water; 0.327 mg/l -

Marine water; 0.327 mg/l -

Intermittent release; 0.327 mg/l -

STP; 6.58 mg/l -

Sediment (Freshwater); 12.46 mg/kg -

Sediment (Marinewater); 12.46 mg/kg -

Soil; 2.31 mg/kg

CAS No. 28182-81-2 Hexamethylene-1,6-diisocyanate Homopolymer

Freshwater: 0.127 mg/l

Marine water: 0.0127 mg/l

Water: Intermittent release: 1.27 mg/l

Fresh water sediment: 266700 mg/kg dry weight

Marine sediment: 26670 mg/kg dry weight

STP (sewage-treatment plant): 38.3 mg/l

Soil: 53182 mg/kg dry weight

Air: No hazard identified

Secondary poisoning:

Does not bioaccumulate.  

Ingredients with biological limit values:

1330-20-7 Xylene (mix)

BMGV

650 mmol/mol creatinine

Medium: urine

Sampling time:

post shift

Parameter:

methyl hippuric acid ·

Additional information: The lists valid during the making were used as basis.

8.2 Exposure controls

Personal protective equipment:

General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin.

Respiratory protection: In the case of hypersensitivity of the respiratory tract (e.g. asthmatics and those who suffer from chronic bronchitis)it is inadvisable to work with the product. When spraying the product, use a respiratory protective device.

Protection of hands:

Conditionally suitable materials for protective gloves:

DIN EN 374-3 fluorinated rubber-FKM:thickness >0.40mm. Breakthrough time: only suitable for splashes. When skin exposure may occur, advice should be sought from the glove supplier on appropriate types and usage times for this product. 

Protective gloves

Material of gloves Conditionally suitable materials for protective gloves: DIN EN 374-3 fluorinated rubber - FKM: thickness >0.04mm. · Penetration time of glove material Only suitable for splashes ·

Eye protection: 

Tightly sealed goggles

SECTION 9: Physical and chemical properties.                                                                                                                         

 9.1 Information on basic physical and chemical properties

General Information ·

Appearance:

Form: Liquid

Colour: Clear ·

Odour: Characteristic ·

Odour threshold: Not determined. ·

pH-value: Not determined. ·

Change in condition Melting point/freezing point: Undetermined.

Initial boiling point and boiling range: 145 °C ·

Flash point: 38 °C ·

Flammability (solid, gas): Not applicable. ·

Ignition temperature: 315 °C ·

Decomposition temperature: Not determined. ·

Auto-ignition temperature: Product is not self igniting. ·

Explosive properties: Product is not explosive. However, formation of explosive air/ vapour mixtures are possible. · Explosion limits: Lower: 1.1 Vol % Upper: 10.8 Vol % ·

Vapour pressure at 20 °C: 6.7 hPa ·

Density at 20 °C: 1.07 g/cm³ ·

Relative density Not determined. ·

Vapour density Not determined. ·

Evaporation rate Not determined. ·

Solubility in / Miscibility with water: NOT MISCIBLE ·

Partition coefficient: n-octanol/water: Not determined. ·

Viscosity: Dynamic at 20 °C: 600 mPas

Kinematic: Not determined. 

Solvent content: Organic solvents: 25.0 %

Solids content: 75.0 % ·

9.2 Other information No further relevant information available.

 

SECTION 10: Stability and reactivity.                                                                                                                                            

10.1 Reactivity No further relevant information available.

10.2 Chemical stability ·

Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. 

10.3 Possibility of hazardous reactions:

Exothermic reaction with amines and alcohols, reacts slowly with water forming CO2.

In closed containers, risk of bursting due to increased pressure,

10.4 Conditions to avoid:

No further relevant information available. 

10.5 Incompatible materials:

Oxidising agents,strongly alkaline and strongly acidic materials, amines, alcohols and water.

10.6 Hazardous decomposition products:

No dangerous decomposition products when stored and handled correctly.

SECTION 11: Toxicological information.                                                                                                                                   

11.1 Information on toxicological effects

Acute toxicity:

Harmful if inhaled.

LD/LC50 values relevant for classification:

28182-81-2 Hexamethylene-1,6-diisocyanate Homopolymer

Oral LD50 >2,500 mg/kg (rat) (OECD Test Guidline 423)

Dermal LD50 >2,000 mg/kg (rat) (OECD Test Guideline 402)

Inhalative LC50/4 h 0.39 mg/l (rat) (Method: OECD Test Guideline 403)

1330-20-7 Xylene (mix)

Oral LD50 5,000 mg/kg (Rat)

Dermal LD50 2,000 mg/kg (rbt)

Inhalative LC50/4 h 4,300 mg/l (Rat)

108-65-6 2-methoxy-1-methylethyl acetate

Oral LD50 >5,000 mg/kg (rat)

Dermal LD50 5,000 mg/kg (Rat)

Inhalative LC50/4 h >10.8 mg/l (Rat)

822-06-0 hexamethylene-1,6 diisocyanate

Oral LD50 746 mg/kg (Rat)

Dermal LD50 >7,000 mg/kg (Rat)

Inhalative LC50/4 h 0.124 mg/l (Rat)

Primary irritant effect:

Skin corrosion/irritation:

Causes skin irritation.

Serious eye damage/irritation:

Causes serious eye irritation.

Respiratory or skin sensitisation:

May cause an allergic skin reaction.

Additional toxicological information:

Based on the properties of the isocyanate content of this product, respiratory exposure may cause acute irritation and / or sensitisation of the respiratory system, resulting in asthmatic symptoms, wheezing and a  tightness of the chest, Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability.

COSHH requires that persons exposed to products containing HDI which is a respiratory sensitiser are subject to appropriate health surveillance. Publications giving guidance on health surveilance are listed in Section 16.

CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity Based on available data, the classification criteria are not met.

Reproductive toxicity Based on available data, the classification criteria are not met.

STOT-single exposure:

May cause respiratory irritation.

STOT-repeated exposure:

May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard Based on available data, the classification criteria are not met.

 

SECTION 12: Ecological information.                                                                                                                                         

12.1 Toxicity

Aquatic toxicity: Acute Fish toxicity

Hexamethylene-1,6-diisocyanate Homopolymer

LC50 > 100 mg/l

Test type: Acute Fish toxicity

Species: Danio rerio (zebra fish)

Exposure duration: 96 h

Method: Directive 67/548/EEC, Annex V, C.1.

Acute toxicity for daphnia

Hexamethylene-1,6-diisocyanate Homopolymer

EC50 > 100 mg/l

Species: Daphnia magna (Water flea)

Exposure duration: 48 h

Method: Directive 67/548/EEC, Annex V, C.2.

Acute toxicity for algae

Hexamethylene-1,6-diisocyanate Homopolymer

ErC50 > 1,000 mg/l

Test type: Growth inhibition Species: scenedesmus subspicatus

Exposure duration: 72 h

Method: DIN 38412

Acute bacterial toxicity

Hexamethylene-1,6-diisocyanate Homopolymer

EC50 3,828 mg/l

Test type: Respiration inhibition

Species: activated sludge

Exposure duration: 3 h

Method: OECD Test Guideline 209

Ecotoxicology Assessment

Hexamethylene-1,6-diisocyanate Homopolymer

Acute aquatic toxicity: Based on available data, the classification criteria are not met.

Chronic aquatic toxicity: There is no evidence of a chronic aquatic toxicity.

Impact on Sewage Treatment: Because of the low bacterial toxicity, there is no risk of an adverse effect on the performance of biological waste water treatment plants.

12.2 Persistence and degradability: No further relevant information available. 

12.3 Bioaccumulative potential: No further relevant information available.

12.4 Mobility in soil No further relevant information available.

Additional ecological information:

General notes:

Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground.

12.5 Results of PBT and vPvB assessment : 

PBT: Not applicable.

vPvB: Not applicable.

12.6 Other adverse effects No further relevant information available.

 

SECTION 13: Disposal considerations.                                                                                                                                           

13.1 Waste treatment methods 

Recommendation:

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

Uncleaned packaging:

Recommendation: Disposal must be made according to official regulations.

 

SECTION 14: Transport information.                                                                                                                                        

4.1 UN-Number

 ADR, IMDG, IATA                               UN1263

14.2 UN proper shipping name

ADR                                                     1263 PAINT RELATED MATERIAL

IMDG, IATA                                         PAINT RELATED MATERIAL

14.3 Transport hazard class(es)

ADR, IMDG, IATA

 

 

 

 

 

 

 

Class                                                       3 Flammable liquids.

Label                                                      3 

14.4 Packing group

ADR, IMDG, IATA                                   III 

14.5 Environmental hazards:

Marine pollutant:                                 No  

14.6 Special precautions for user      Warning: Flammable liquids.

Danger code (Kemler):                        30 ·

EMS Number:                                      F-E,S-E ·

Stowage Category                               A · 14.7

Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable.

Transport/Additional information:

ADR · Limited quantities (LQ)             5L

Excepted quantities (EQ)                    Code: E1

                                                               Maximum net quantity per inner packaging: 30 ml

                                                               Maximum net quantity per outer packaging: 1000 ml

Transport category                             3

Tunnel restriction code                      D/E

IMDG ·

Limited quantities (LQ)                       5L

Excepted quantities (EQ)                   Code: E1

                                                               Maximum net quantity per inner packaging: 30 ml

                                                               Maximum net quantity per outer packaging: 1000 ml

UN "Model Regulation":                     UN 1263 PAINT RELATED MATERIAL, 3, III

 

SECTION 15: Regulatory information.                                                                                                                                    

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 

Directive 2012/18/EU

Named dangerous substances - ANNEX I None of the ingredients is listed.

Seveso category P5c FLAMMABLE LIQUIDS 

Qualifying quantity (tonnes) for the application of lower-tier requirements 5,000 t

Qualifying quantity (tonnes) for the application of upper-tier requirements 50,000 t

REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3 ·

National regulations: ·

Technical instructions (air):

Class 1, Share in % I 0.4,  NK 25.0 ·

Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.

15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

 

SECTION 16: Other information.                                                                                                                                                    

Publications available fron the HSE:

Breath Freely, INDG 172; respiratory Sensitisers and COSHH - a guide for employers INDG95; Isocyanates - health hazards and precautionary measures, EH11 etc.

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. 

Full text of H-Statements referred to under sections 2 and 3:

H226 Flammable liquid and vapour.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H312 Harmful in contact with skin.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H330 Fatal if inhaled.

H332 Harmful if inhaled.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H335 May cause respiratory irritation.

H373 May cause damage to organs through prolonged or repeated exposure.

Department issuing SDS: Product safety department: LABORATORY

 Contact: Health & Safety Officer

Abbreviations and acronyms:

RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)

ICAO: International Civil Aviation Organisation

ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

GHS: Globally Harmonised System of Classification and Labelling of Chemicals

EINECS: European Inventory of Existing Commercial Chemical Substances

ELINCS: European List of Notified Chemical Substances

CAS: Chemical Abstracts Service (division of the American Chemical Society)

DNEL: Derived No-Effect Level (REACH)

PNEC: Predicted No-Effect Concentration (REACH)

LC50: Lethal concentration, 50 percent

LD50: Lethal dose, 50 percent

PBT: Persistent, Bioaccumulative and Toxic

vPvB: very Persistent and very Bioaccumulative

Flam. Liq. 3: Flammable liquids – Category 3

Acute Tox. 2: Acute toxicity – Category 2

Acute Tox. 4: Acute toxicity – Category 4

Skin Irrit. 2: Skin corrosion/irritation – Category 2

Eye Irrit. 2: Serious eye damage/eye irritation – Category 2

Resp. Sens. 1: Respiratory sensitisation – Category 1

Skin Sens. 1: Skin sensitisation – Category 1

STOT SE 3: Specific target organ toxicity (single exposure) – Category 3

STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2

Asp. Tox. 1: Aspiration hazard – Category 1

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